Structural dependence of microwave dielectric properties of spinel structured Mg2(Ti1-xSnx)O4 solid solutions: Crystal structure refinement,Raman spectra study and complex chemical bond theory

Mg₂(Ti_1-xSn_x)O₄ (x?=?0–1) ceramics were prepared through conventional solid-state method. This paper focused on the dependence of microwave dielectric properties on crystal structural characteristics via crystal structure refinement, Raman spectra study and complex chemical bond theory. XRD spectrums delineated the phase information of a spinel structure, and structural characteristic of these compositions were achieved with the help of Rietveld refinements. Raman spectrums were used to depict the correlations between vibrational phonon modes and dielectric properties. The variation of permittivity is ascribed to the Mg₂(Ti_1-xSn_x)O₄ average bond covalency. The relationship among the B-site octahedral bond energy, tetrahedral bond energy and temperature coefficient are discussed by defining on the change rate of bond energy and the contribution rate of octahedral bond energy. The quality factor is affected by systematic total lattice energy, and the research of XPS patterns illustrated that oxygen vacancies can be effectively restrained in rich oxygen sintering process. Obviously, the microwave dielectric properties of Mg₂(Ti_1-xSn_x)O₄ compounds were obtained (${\epsilon }_r$= 12.18, $Q\times f$?=?170,130?GHz, ${\tau }_f$?=??53.1?ppm/°C, x?=?0.2).     

制备条件对硅基介孔分子筛孔结构的影响

采用溶剂热法制备了硅基介孔分子筛材料,较系统地考察了晶化温度、晶化时间及焙烧温度等因素对其结构的影响,并利用N2吸附手段进行了表征.结果表明,晶化温度和晶化时间能明显影响硅基介孔材料的结构,而过高的焙烧温度易导致介孔结构的塌陷.     

SIMPLIS环境中开关电源集成电路控制器模型的开发及应用

介绍现代开关电源行业仿真工作的意义和现状,以及专用仿真软件包SIM etrix/SIMPLIS的优点和不足。通过实例给出SIMPLIS环境中集成电路控制芯片的建模过程,并就其中的关键技术予以简单讨论。     

渤海绥中油田J3井疏水缔合聚合物驱数值模拟研究

为了进一步提高渤海油田J3井区缔合聚合物驱的技术经济效果,在渤海油田室内配方和先导性矿场试验研究基础上,利用化学驱油藏数值模拟软件FAPMS,分析和研究了高浓度缔合聚合物前置段塞、主段塞的大小和浓度以及段塞组合方式对驱油效果的影响,优化设计了渤海绥中油田J3井区块矿场试验的最佳注入程序及段塞大小。结果表明,通过对不同浓度的疏水缔合聚合物注入的前置段塞及主段塞和梯度式后续段塞的优化后,原油采收率比未优化时提高了约10个百分点。研究表明,渤海油田应该高度重视聚合物驱的注入方式和段塞优化设计,进一步提高聚合物的技术经济效果。     

Blind estimation of OFDM carrier frequency offset via oversampling

Blind deterministic estimation of the orthogonal frequency division multiplexing (OFDM) frequency offset via oversampling is proposed in this paper. This method utilizes the intrinsic phase shift of neighboring sample points incurred by the frequency offset that is common among all subcarriers. The proposed method is data efficient - it requires only a single OFDM symbol to achieve reliable estimation, hence making it more suitable to systems with stringent delay requirement and mobility-induced channel variation. The proposed scheme is devised to perfectly retrieve frequency offset in the absence of noise. Quite remarkably, we show that in the presence of channel noise, this intuitive scheme is indeed the maximum likelihood estimate of the carrier frequency offset. The possible presence of virtual carriers are also accommodated in the system model, and some interesting observations are obtained. The Cramer-Rao lower bound is derived for the oversampling-based signal model, and we show through numerical simulation that the proposed algorithm is efficient. Practical issues such as identifiability, the front-end filter bandwidth, and the possible presence of correlated noises are also carefully addressed.     

Mining predecessor–successor rules from DAG data

Data mining extracts implicit, previously unknown, and potentially useful information from databases. Many approaches have been proposed to extract information, and one of the most important ones is finding association rules. Although a large amount of research has been devoted to this subject, none of it finds association rules from directed acyclic graph (DAG) data. Without such a mining method, the hidden knowledge, if any, cannot be discovered from the databases storing DAG data such as family genealogy profiles, product structures, XML documents, task precedence relations, and course structures. In this article, we define a new kind of association rule in DAG databases called the predecessor–successor rule, where a node x is a predecessor of another node y if we can find a path in DAG where x appears before y. The predecessor–successor rules enable us to observe how the characteristics of the predecessors influence the successors. An approach containing four stages is proposed to discover the predecessor–successor rules. © 2006 Wiley Periodicals, Inc. Int J Int Syst 21: 621–637, 2006.     

大型往复式压缩机的配管设计

大型往复式压缩机功率大、占地面积大,管道振动问题也更为突出。笔者结合实践经验,对大型往复式压缩机的配管设计进行探讨,说明了平面布置与管道防振设计的密切关系,并介绍了管道防振设计的方法和步骤,以及相对简单的复杂管系气柱固有频率的转移矩阵计算方法。     

Data-efficient blind OFDM channel estimation using receiver diversity

We investigate non data-aided channel estimation for cyclically prefixed orthogonal frequency division multiplexing (OFDM) systems. By exploiting channel diversity using only two receive antennas, a blind deterministic algorithm is proposed. Identifiability conditions are derived that guarantee the perfect channel retrieval in the absence of noise. In the presence of noise, the proposed method has the desired property of being data efficient-only a single OFDM block is needed to achieve good estimation performance for a wide range of SNR values. The algorithm is also robust to input symbols as it does not have any restriction on the input symbols with regard to their constellation or their statistical properties. In addition, this diversity-based algorithm is computationally efficient, and its performance compares favorably to most existing blind algorithms.     

SrTiO3基压敏电阻的研究及其在武器系统中的应用

电子设备的广泛使用带来的设备干扰及浪涌冲击等问题使人们开始关注SrTiO3基压敏电阻器件材料的开发.本文介绍了SrTiO3基压敏电阻的一般制造配方和工艺流程.和ZnO基压敏电阻相比,此材料在低压领域具有更优良的电气性能,如较大的电容量(C=10～150nF);在高于电压临界值又具有较低压敏电压;非线性系数在5～43之间可调;耐浪涌能量大;并且具有自复位特性.这些特性使得它具有高频噪声吸收、前沿快速上升型脉冲噪声吸收和浪涌吸收等功能.针对武器系统的高性能要求,本文提出了SrTiO3基压敏电阻在直流电机消噪、电源输入端、吸收电感性负载开关浪涌、旁路电容器、通信线路防护、防止电涌冲击等方面的应用.     

化肥厂合成气及重整氢真空变压吸附制取高纯度氢气

从设计、生产操作和经济效益3个方面阐述了以化肥厂合成气及重氢为原料，通过真空变压吸附（VPSA）装置制取高纯度氢的过程。工业应用结果表明，该制氢工艺是一项操作简便灵活，制氢费用较低的工艺路线。VPSA装置技术和设计上的特点能够保证大的操作弹性、高的产品氢纯度和较高的氢气回收率。在36％－51％的低限负荷下，通过适当调整吸附时间，可获得纯度99％的氢气产品，89％－92％的氢气回收率。